发明授权
US4734119A Novel phosphorus compounds for protecting cultivated plants from the
phytotoxic action of herbicides
失效
用于保护栽培植物免受除草剂植物毒性作用的新型磷化合物
- 专利标题: Novel phosphorus compounds for protecting cultivated plants from the phytotoxic action of herbicides
- 专利标题(中): 用于保护栽培植物免受除草剂植物毒性作用的新型磷化合物
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申请号: US669412申请日: 1984-11-08
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公开(公告)号: US4734119A公开(公告)日: 1988-03-29
- 发明人: Peter J. Diel , Ludwig Maier
- 申请人: Peter J. Diel , Ludwig Maier
- 申请人地址: NY Ardsley
- 专利权人: Ciba-Geigy Corporation
- 当前专利权人: Ciba-Geigy Corporation
- 当前专利权人地址: NY Ardsley
- 优先权: CHX6135/83 19831115; CHX2748/84 19840606
- 主分类号: A01N25/32
- IPC分类号: A01N25/32 ; C07F9/30 ; C07F9/32 ; C07F9/38 ; C07F9/40 ; C07F9/53 ; A01N57/04 ; C07C125/065 ; C07F9/02 ; C07F9/28
摘要:
Novel acylated hydrazinomethylphosphonic acids, hydrazinomethylphosphonates, hydrazinomethylphosphinic acids, hydrazinomethylphosphinates or hydrazinomethylphosphine oxides of formula I below are able as "antidotes" or "safeners" to protect cultivated plants from the phytotoxic action of herbicides. Suitable crops are preferably maize, sorghum, cereals, rice and soybeans and the herbicides employed are in particular chloroacetanilides.The acylated hydrazinomethylphosphonates, hydrazinomethylphosphinates or hydrazinomethylphosphine oxides have the formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently hydroxy, alkyl, aryl, phenylalkyl, alkoxy, alkenyloxy, alkynyloxy, aryl or phenylalkoxy, the radicals of which may be substituted,R.sub.3 is a halogenated alkanoyl or alkenoyl radicalR.sub.4 is hydrogen, a halogenated alkanoyl or alkenoyl radical or an alkyl, alkenyl or phenylalkyl radical, or an alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl or phenylcarbonyl radical which may be unsubstituted or substituted or is an alkoxycarbonyl or phenylalkoxycarbonyl radical which may also be unsubstituted or substituted or is an alkoxycarbonyl or phenylakoxycarbonyl radical which may also be substituted,R.sub.5 is hydrogen or an alkyl, alkenyl or alkynyl radical which may also be substituted,R.sub.9 is hydrogen, alkyl or phenyl which is unsubstituted or substituted andR.sub.10 is hydrogen or alkyl.