发明授权
- 专利标题: Preparation of 1,1,2-trialkoxyethanes
- 专利标题(中): 1,1,2-三烷氧基乙醚的制备
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申请号: US73999申请日: 1987-07-16
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公开(公告)号: US4755625A公开(公告)日: 1988-07-05
- 发明人: Robert Maerkl , Werner Bertleff , Rudolf Kummer
- 申请人: Robert Maerkl , Werner Bertleff , Rudolf Kummer
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX3627776 19860816
- 主分类号: C07B61/00
- IPC分类号: C07B61/00 ; B01J31/00 ; B01J31/20 ; B01J31/24 ; C07C41/00 ; C07C41/48 ; C07C43/315 ; C07C67/00 ; C07D317/22 ; C07D319/06 ; C07D321/06
摘要:
1,1,2-trialkoxyethanes I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.8 -alkyl and R.sup.1 and R.sup.2 may furthermore be bonded to one another to form a 5-membered to 7-membered ring, are prepared by reacting a formaldehyde dialkyl acetal II with carbon monoxide and hydrogen, from 0.5 to 1.5 moles of hydrogen being used per mole of carbon monoxide, and with not less than 1 mole of alcohol R.sup.3 OH per mole of formaldehyde dialkyl acetal under superatmospheric pressure and at elevated temperatures in the presence of a catalyst which is formed from a cobalt carbonyl compound and a trivalent organic compound of the formula III ##STR2## where A is phosphorus, arsenic, antimony or bismuth and R.sup.4, R.sup.5 and R.sup.6 are each an organic radical.
公开/授权文献
- USD405588S Seat cushion 公开/授权日:1999-02-16