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US4786697A Molecular weight distribution modification in a tubular reactor 失效
管式反应器中的分子量分布改性

Molecular weight distribution modification in a tubular reactor
摘要:
Polymodal MWD ethylene copolymer comprising at least two modes of differing molecular weights. Each mode has at least one of M.sub.w /M.sub.n of less than 2.0, and a M.sub.z /M.sub.w of less than 1.8. The polymodal character of the copolymer is achieved by either (1) withdrawing polymer modes from the reactor from at least one takeoff port, and blending such modes with the reactor effluent, or (2) utilizing at least two catalyst species in the reaction to produce modes of differing molecular weights.
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