A process for the production of hydrogen peroxide according to the anthraquinone process. According to the process certain alkyl substituted caprolactames are used as solvents, and particularly as solvents for anthrahydroquinones. The substituted caprolactames, which for example can be hexyl caprolactam and octyl caprolactam, give a very good solubility for anthrahydroquinones and also for anthraquinones. The compounds can be used as the sole solvent at the production of hydrogen peroxide or in combination with conventionally used solvents such as hydrocarbons.