发明授权
US4803036A Process for blow-molding and heat setting of polyester hollow formed body 失效
聚酯中空成型体的吹塑和热定形工艺

Process for blow-molding and heat setting of polyester hollow formed body
摘要:
A process for the preparation of a heat-resistant polyester hollow formed body, which comprises mounting a preform of a thermoplastic polyester composed mainly of ethylene terephthalate units, which is maintained at a temperature where high-speed drawing is possible but whitening can be prevented, especially at a temperature represented by the following formula:T=k(100.multidot.IV-8.multidot.DEG+42) (1)wherein IV stands for the intrinsic viscosity (dl/g) of the thermoplastic polyester, DEG stands for the content (% by weight) of diethylene glycol units in the thermoplastic polyester, k is a number of from 0.95 to 1.05, and T stands for the temperature (.degree.C.) of the preform, in a hollow forming mold maintained at a temperature as high as possible within the range where a final hollow formed body can be withdrawn without deformation substantially under non-cooling, blowing air maintained at a temperature higher than the preform temperature into the preform to effect stretch drawing and expansion drawing so that the drawing speed in the axial direction is at least 250%/sec and the drawing speed in the circumferential direction is at least 450%/sec, and effecting heat setting while the preform is being draw-formed.
公开/授权文献
信息查询
0/0