发明授权
- 专利标题: Integrated etherification process with recycle post treatment
- 专利标题(中): 综合醚化过程与回收后处理
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申请号: US211317申请日: 1988-06-24
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公开(公告)号: US4816607A公开(公告)日: 1989-03-28
- 发明人: Bipin V. Vora , Peter R. Pujado , Richard E. Conser
- 申请人: Bipin V. Vora , Peter R. Pujado , Richard E. Conser
- 申请人地址: IL Des Plaines
- 专利权人: UOP Inc.
- 当前专利权人: UOP Inc.
- 当前专利权人地址: IL Des Plaines
- 主分类号: C07C5/27
- IPC分类号: C07C5/27 ; C07C41/06
摘要:
A multistep hydrocarbon conversion process for the production of ethers including methyl tertiary butyl ether (MTBE) from light paraffins and alcohols is disclosed. A mixture of C.sub.4 isoparaffins, normal paraffins, an etherification recycle and butane isomerization effluent enter a deisobutanizer column. Normal paraffins withdrawn from the fractionator are isomerized and returned to the fractionator, and isoparaffins are withdrawn from the fractionator and dehydrogenated. The resulting olefins enter an etherification zone for reaction of isobutene with a C.sub.2 -C.sub.5 alcohol. Unreacted paraffins and olefins comprise a portion of the etherification effluent entering the deisobutanizer. After separation for recovery of the ether product, unreacted paraffins and olefins are passed through a dehydrogenation zone for saturation of the olefins and then returned to the deisobutanizer column. Normal butanes are withdrawn as a sidecut from the deisobutanizer. The sidecut passes to an isomerization zone and a mixture of isobutane and normal butane is recycled to the deisobutanizer. In a highly preferred embodiment, spent catalyst from the isomerization zone fulfills the catalyst requirement of the dehydrogenation zone.
公开/授权文献
- US4361937A Cable banding lock ring 公开/授权日:1982-12-07
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