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US4826956A Process for the preparation of copoly(arylene sulfide) using an oxygen-containing gas 失效
使用含氧气体制备共聚(亚芳基硫醚)的方法

Process for the preparation of copoly(arylene sulfide) using an
oxygen-containing gas
摘要:
A process for producing a copoly(arylene sulfide) corresponding to the structure[--A--S--).sub.1-x (--A--S--S--).sub.x ].sub.nwherein A is a divalent substituted or unsubstituted aromatic radical, x is in the range of 0.5 to 0.001 and n is at least 200, comprising reacting within a reaction zone a mixture of a diiodoaromatic compound and elemental sulfur at a polymer producing temperature wherein the reaction zone contains an oxygen-containing gas flowing at a rate in the range of 0.001 to 0.08 ft3/hr/mol of oxygen per mole of sulfur.
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