发明授权
- 专利标题: Process for polymerizing olefins
- 专利标题(中): 烯烃聚合方法
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申请号: US226729申请日: 1988-08-01
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公开(公告)号: US4831091A公开(公告)日: 1989-05-16
- 发明人: Masato Harada , Makoto Iijima , Noriaki Saito
- 申请人: Masato Harada , Makoto Iijima , Noriaki Saito
- 申请人地址: JPX Osaka
- 专利权人: Chisso Corporation
- 当前专利权人: Chisso Corporation
- 当前专利权人地址: JPX Osaka
- 优先权: JPX60-51507 19850314
- 主分类号: C08F4/00
- IPC分类号: C08F4/00 ; C08F4/60 ; C08F4/64 ; C08F4/658 ; C08F10/00
摘要:
A process for producing polyolefins having a high stereoregularity, no smell and a good particulate form, without needing removal of catalyst residue contained in the resulting polyolefins, which process comprises polymerizing olefins by the use of a catalyst obtained by combining a solid product (II) as a solid catalyst component prepared through the following reaction steps I, II and III, with an organoaluminum compound component and an organic silicon compound component having Si-O-C bond: Step I of mixing and dissolving .circle.a an anhydrous Mg dihalide, .circle.b a specified orthotitanic acid ester or/and a specified polytitanic acid ester and .circle.c a saturated or unsaturated, mono- or polyhydroxy alcohol of 1.about.20 C in an inert hydrocarbon solvent to obtain a component (A), Step II of mixing (A) with a component (B) consisting of .circle.d an aliphatic or aromatic monocarboxylic acid ester, .circle.e a specified halogenated aluminum and .circle.f a specified halogenated silicon to obtain a solid product (I), and Step III of reacting (I) with a component (C) consisting of .circle.g a specified halogenated titanium or/and .circle.h a specified halogenated vanadyl or a specified vanadium halide to obtain the solid product (II).