发明授权
US4845302A Preparation of 5H-dibenzo[a,d]cyclohepten-5-ones 失效
制备5H-二苯并[a,d]环庚烯-5-酮

Preparation of 5H-dibenzo[a,d]cyclohepten-5-ones
摘要:
5H-Dibenzo[a,d]cyclohepten-5-ones (I) ##STR1## (A and B being radicals for completing aromatic ring systems) are prepared by converting (Z)-2-(2-arylethenyl)arylcarboxylic acids (II) ##STR2## or E/Z-isomer mixtures thereof with a halogenating agent for carboxylic acids at from (-30.degree.) to +120.degree. C. to the corresponding carbonyl halides (III) ##STR3## where X is halogen, and cyclizing said carbonyl halides at from 0.degree. to 100.degree. C. in the presence of a Lewis acid.
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