发明授权
- 专利标题: Preparation of 5H-dibenzo[a,d]cyclohepten-5-ones
- 专利标题(中): 制备5H-二苯并[a,d]环庚烯-5-酮
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申请号: US134885申请日: 1987-12-18
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公开(公告)号: US4845302A公开(公告)日: 1989-07-04
- 发明人: Marco Thyes , Gerd Steiner
- 申请人: Marco Thyes , Gerd Steiner
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengsellschaft
- 当前专利权人: BASF Aktiengsellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX3644462 19861224
- 主分类号: B01J27/125
- IPC分类号: B01J27/125 ; C07B31/00 ; C07B41/06 ; C07B61/00 ; C07C45/00 ; C07C45/46 ; C07C45/65 ; C07C49/675 ; C07C49/697 ; C07C49/755 ; C07C67/00
摘要:
5H-Dibenzo[a,d]cyclohepten-5-ones (I) ##STR1## (A and B being radicals for completing aromatic ring systems) are prepared by converting (Z)-2-(2-arylethenyl)arylcarboxylic acids (II) ##STR2## or E/Z-isomer mixtures thereof with a halogenating agent for carboxylic acids at from (-30.degree.) to +120.degree. C. to the corresponding carbonyl halides (III) ##STR3## where X is halogen, and cyclizing said carbonyl halides at from 0.degree. to 100.degree. C. in the presence of a Lewis acid.
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