发明授权
- 专利标题: Crosslinkable, fluorine-containing copolymers as binders for highly weather-resistant surface coatings
- 专利标题(中): 可交联的含氟共聚物作为高耐候性表面涂料的粘合剂
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申请号: US141569申请日: 1988-01-06
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公开(公告)号: US4859755A公开(公告)日: 1989-08-22
- 发明人: Michael Schlipf , Albrecht Manz , Gernot Lohr
- 申请人: Michael Schlipf , Albrecht Manz , Gernot Lohr
- 申请人地址: DEX Frankfurt am Main
- 专利权人: Hoechst Aktiengesellschaft
- 当前专利权人: Hoechst Aktiengesellschaft
- 当前专利权人地址: DEX Frankfurt am Main
- 优先权: DEX3700548 19870110
- 主分类号: C08F16/14
- IPC分类号: C08F16/14 ; C08F18/02 ; C08F214/26 ; C08F216/14 ; C08F218/04 ; C08F218/10 ; C09D127/12 ; C09D129/00 ; C09D131/02
摘要:
Crosslinkable, fluorine-containing copolymers, comprising:(a) 15 to 70 mol % of copolymerized units of a vinyl ester of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 are branched or straight-chain alkyl radicals or cycloalkyl radicals, at most one of these radicals is hydrogen and at least one of these radicals is a methyl group, and where, furthermore, the entire acyl radical of the vinyl ester contains at least 9 and at most 28 carbon atoms,(b) 5 to 50 mol % of copolymerized units of a hydroxyalkyl vinyl ether of the formulaCH.sub.2 .dbd.CH--O--R.sup.4 --OH in which R.sup.4 OH is a branched or straight-chain hydroxy-alkyl group having 1 to 6 carbon atoms, and(c) copolymerized units of tertrafluoroethylene in an amount which makes up the sum of components (a) plus (b) plus (c) to 100, but with the proviso that at least 10 mol % of copolymerized units of tetrafluoroethylene are present in the copolymer.From these, highly weather-resistant surface-coating compositions are obtained on addition of crosslinking agents, solvents and conventional additives.