发明授权
US4882401A Slow gel/cure systems based on dialkylzinc for dicyclopentadiene polymerization 失效
用于二环戊二烯聚合的基于二烷基锌的缓慢凝胶/固化体系

  • 专利标题: Slow gel/cure systems based on dialkylzinc for dicyclopentadiene polymerization
  • 专利标题(中): 用于二环戊二烯聚合的基于二烷基锌的缓慢凝胶/固化体系
  • 申请号: US250209
    申请日: 1988-09-28
  • 公开(公告)号: US4882401A
    公开(公告)日: 1989-11-21
  • 发明人: Andrew Bell
  • 申请人: Andrew Bell
  • 申请人地址: DE Wilmington
  • 专利权人: Hercules Incorporated
  • 当前专利权人: Hercules Incorporated
  • 当前专利权人地址: DE Wilmington
  • 主分类号: C08G61/06
  • IPC分类号: C08G61/06 C08F4/50 C08G61/08 C08G61/12
Slow gel/cure systems based on dialkylzinc for dicyclopentadiene
polymerization
摘要:
A process for preparing molded objects wherein a liquid reaction mass comprised of a metathesis polymerizable cycloolefin, a metathesis polymerization catalyst, a catalyst activator and a reaction rate moderator are charged to a mold wherein polymerization will take place, the improvement wherein said catalyst activator comprises a dialkylzinc compound. Significantly increased gel and cure times are obtained with the dialkylzinc compounds as compared to the use of aluminum alkyl activator compounds. The gel and cure times may be further controlled by the addition of a phenolic compound to the tungsten or molybdenum compound or by the addition of a Lewis base.
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