发明授权
US4883910A Oxidation of organics by a vanadium containing heteropolyanion compound
失效
通过含钒杂多阴离子化合物氧化有机物
- 专利标题: Oxidation of organics by a vanadium containing heteropolyanion compound
- 专利标题(中): 通过含钒杂多阴离子化合物氧化有机物
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申请号: US714196申请日: 1985-03-20
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公开(公告)号: US4883910A公开(公告)日: 1989-11-28
- 发明人: William C. Seidel
- 申请人: William C. Seidel
- 申请人地址: DE Wilmington
- 专利权人: E. I. Du Pont De Nemours and Company
- 当前专利权人: E. I. Du Pont De Nemours and Company
- 当前专利权人地址: DE Wilmington
- 主分类号: B01J23/22
- IPC分类号: B01J23/22 ; B01J23/24 ; C07C51/31
摘要:
An organic compound having a cyclic aliphatic moiety is oxidized with a vanadium containing heteropolyanion compound having the formulaA.sub.m XY.sub.12-n V.sub.n.sup.+5 O.sub.40whereinA is H, Li, K or Na:X is P.sup.+5, Si.sup.+4, Ge.sup.+4 or B.sup.+3 ;Y is Mo or W;n is an integer from 1 to 10; andm is 3+n where X is P.sup.+5 or As.sup.+5, 4+n where X is Si.sup.+4 or Ge.sup.+4, and 5+n where X is B+3.No metal catalyst is required. Exemplary is the oxidation of cyclohexanone, cyclohexanol, or any combination thereof to obtain adipic acid.
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