发明授权
US4918038A Process for the production of polyethylene with a broad and/or bimodal
molecular weight distribution
失效
用于生产具有宽和/或双峰分子量分布的聚乙烯的方法
- 专利标题: Process for the production of polyethylene with a broad and/or bimodal molecular weight distribution
- 专利标题(中): 用于生产具有宽和/或双峰分子量分布的聚乙烯的方法
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申请号: US114040申请日: 1987-10-29
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公开(公告)号: US4918038A公开(公告)日: 1990-04-17
- 发明人: Sari-Beth Samuels , Frederick J. Karol
- 申请人: Sari-Beth Samuels , Frederick J. Karol
- 申请人地址: CT Danbury
- 专利权人: Union Carbide Chemicals and Plastics Company Inc.
- 当前专利权人: Union Carbide Chemicals and Plastics Company Inc.
- 当前专利权人地址: CT Danbury
- 主分类号: C08F4/638
- IPC分类号: C08F4/638 ; C08F4/60 ; C08F4/62 ; C08F4/658 ; C08F4/68 ; C08F10/00 ; C08F10/02 ; C08F110/02
摘要:
A process for the production of an ethylene homopolymer or copolymer comprising passing ethylene with or without at least one alpha-olefin comonomer having 3 or more carbon atoms into contact with a mixed catalyst system, under polymerization conditions, said mixed catalyst system comprising:(a) the reaction product of (i) a vanadium halide having the formula VX.sub.3 wherein X is chlorine, bromine, or iodine and each X is alike or different; (ii) a modifier having the formula BX.sub.3 or AlR.sub.(3-a) X.sub.a and (iii) an electron donor(b) one of the following:(i) a complex having the formula ZrMg.sub.b X.sub.c (ED).sub.d ; or(ii) a vanadium oxy compound having the formula VOX.sub.3, VOX.sub.2, VOX, or VO.sub.2 X wherein X is as defined above, or VO(OR).sub.3(c) a hydrocarbyl aluminum cocatalyst; and(d) a halocarbon promoter having the formula R.sub.e CX.sub.(4-e) wherein R is hydrogen or an unsubstituted or halo substituted alkyl radical having 1 to 6 carbon atoms; each R is alike or different; X is chlorine, bromine, iodine, or fluorine; each X is alike or different and e is 0, 1, or 2 provided that, if no fluorine is present, e is 2.
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