发明授权
- 专利标题: Method for preparing functionalized block copolymers
- 专利标题(中): 官能化嵌段共聚物的制备方法
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申请号: US211748申请日: 1988-06-27
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公开(公告)号: US4921625A公开(公告)日: 1990-05-01
- 发明人: John E. Gorman , John A. Morris
- 申请人: John E. Gorman , John A. Morris
- 申请人地址: TX Houston
- 专利权人: Shell Oil Company
- 当前专利权人: Shell Oil Company
- 当前专利权人地址: TX Houston
- 主分类号: C08F2/00
- IPC分类号: C08F2/00 ; B29C35/00 ; C08F8/46 ; C08F287/00 ; C08F291/00
摘要:
A process for incorporating carboxy and/or carboxyl derivative functionality into a hydrocarbon polymer which is substantially free of ethylenic unsaturation. The functionalization is accomplished by contacting the functionalizing agent or agents with the polymer in the presence of a free radical initiator in a blending apparatus capable of imparting high mechanical energy into the reaction medium. The blending apparatus is preferably an extruder and most preferably a non-intermeshing twin screw extruder. The amount of degradation resulting from the presence of a free radical initiator and the high mechanical shear at the elevated temperatures employed during the contacting is reduced by effecting the contacting in a suitable diluent. Similarly, the amount of polymer crosslinking and/or coupling is reduced through the use of a suitable diluent. The polymer is maintained in the molten phase during the reaction.
公开/授权文献
- USD269458S Incision approximator 公开/授权日:1983-06-21
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