发明授权
US4921989A .OMEGA.silylalkynyl silane compound and method for preparation thereof
失效
OMEGA甲硅烷基炔基硅烷化合物及其制备方法
- 专利标题: .OMEGA.silylalkynyl silane compound and method for preparation thereof
- 专利标题(中): OMEGA甲硅烷基炔基硅烷化合物及其制备方法
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申请号: US359897申请日: 1989-06-01
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公开(公告)号: US4921989A公开(公告)日: 1990-05-01
- 发明人: Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Yasuhisa Tanaka
- 申请人: Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Yasuhisa Tanaka
- 申请人地址: JPX Tokyo
- 专利权人: Shin-Etsu Chemical Co., Ltd.
- 当前专利权人: Shin-Etsu Chemical Co., Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX63-136006 19880602
- 主分类号: C07F7/12
- IPC分类号: C07F7/12 ; C07F7/18
摘要:
The novel organosilicon compound of the invention is an .omega.-silylalkynyl silane compound represented by the general formula R.sub.3 SiC.tbd.C(CH.sub.2).sub.n Si(CH.sub.3).sub.m X.sub.3-m, in which each R is, independently from the others, a hydrogen atom, lower alkyl group or aryl group, X is a halogen atom or a lower alkoxy group, the subscript m is 0,1 or 2 and the subscript n is an integer in the range from 10 to 30 which forms a uniform monomolecular layer on a substrate surface with silyl ethynyl groups arranged in alignment. The compound can be prepared by a Grignard reaction starting form an .omega.-silylalkynyl halide represented by the general formula R.sub.3 SiC.tbd.C(CH.sub.2).sub.n Y, in which R and n each have the same meaning as defined above and Y is a halogen atom, and a methyl alkoxy or halosilane of the formula (CH.sub.3).sub.m SiX.sub.4-m, in which X and m each have the same meaning as defined before.
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