发明授权
US4933401A Catalyst composition for polymerization of conjugated diene and process
for producing conjugated diene polymer
失效
用于共轭二烯聚合的催化剂组合物和共轭二烯聚合物的制备方法
- 专利标题： Catalyst composition for polymerization of conjugated diene and process for producing conjugated diene polymer
- 专利标题（中）： 用于共轭二烯聚合的催化剂组合物和共轭二烯聚合物的制备方法
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申请号： US314130申请日： 1989-02-23
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公开(公告)号： US4933401A公开(公告)日： 1990-06-12
- 发明人: Iwakazu Hattori , Noboru Shimada , Noboru Oshima , Mitsuhiko Sakakibara
- 申请人： Iwakazu Hattori , Noboru Shimada , Noboru Oshima , Mitsuhiko Sakakibara
- 申请人地址： JPX Tokyo
- 专利权人： Japan Synthetic Rubber Co., Ltd.
- 当前专利权人： Japan Synthetic Rubber Co., Ltd.
- 当前专利权人地址： JPX Tokyo
- 优先权： JPX63-43570 19880226
- 主分类号： C08F2/06
- IPC分类号： C08F2/06 ; C08F4/48 ; C08F36/04
摘要：
A catalyst composition for polymerizing a conjugated diene which comprises the following (a), (b) and (c) components:(a) an organolithium-aluminum compound represented by the formula:LiAlR.sup.1 R.sup.2 R.sup.3 R.sup.4(b) an organobarium-aluminum compound represented by the formula:Ba(AlR.sup.1 R.sup.2 R.sup.3 R.sup.4).sub.2 or Ba[AlR.sup.1 R.sup.2 R.sup.3 (OR.sup.4)].sub.2(c) a lithium alkoxide represented by the formula:LiOR.sup.5 The conjugated diene polymer or copolymer obtained by polymerizing a conjugated diene alone or in combination with other monomer with the above catalyst composition in an inert organic solvent has a high trans-1,4 bond content, a low vinyl bond content and a low cis-1,4 bond content.
公开/授权文献
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