发明授权
US4963632A Mixed micellar process for preparing hydrophobically associating polymers
失效
用于制备疏水缔合聚合物的混合胶束方法
- 专利标题: Mixed micellar process for preparing hydrophobically associating polymers
- 专利标题(中): 用于制备疏水缔合聚合物的混合胶束方法
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申请号: US291803申请日: 1988-12-29
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公开(公告)号: US4963632A公开(公告)日: 1990-10-16
- 发明人: Jan Bock , Paul L. Valint
- 申请人: Jan Bock , Paul L. Valint
- 申请人地址: NJ Florham Park
- 专利权人: Exxon Research and Engineering Company
- 当前专利权人: Exxon Research and Engineering Company
- 当前专利权人地址: NJ Florham Park
- 主分类号: C08F2/10
- IPC分类号: C08F2/10 ; C08F20/52 ; C08F28/00 ; C08F212/00 ; C08F212/08 ; C08F220/04 ; C08F220/06 ; C08F220/56 ; C08F220/58 ; C08F228/02
摘要:
A homogeneous micellar free radical polymerization process for the formation of a terpolymer having the structure of: ##STR1## wherein S is selected from the group consisting of SO.sub.3 M, phenyl SO.sub.3 M, CONHC(CH.sub.3).sub.2 CH.sub.2 SO.sub.3 M or COOM; M is selected from the group consisting of Groups IA, 1B, IIA and IIB of the Periodic Table of Elements, R.sub.1 is a C.sub.1 to C.sub.10 alkyl, cycloalkyl or aralkyl group, R.sub.2 is hydrogen or a C.sub.4 to C.sub.18 alkyl, cycloalkyl or aralkyl group, x is about 10 to about 90 mole %, y is about 0.1 to about 60 mole %, and z is about 0.2 to about 10 mole % which comprises the steps of forming a mixture of an anionic surfactant, a nonionic surfactant, ##STR2## under a nitrogen atmosphere; adding deoxygenated water to said mixture to form a homogeneous reaction solution; adding free radical initiator to said homogeneous reaction solution to initiate polymerization of said monomers; terpolymerizing said monomers at a sufficient temperature and for a sufficient period of time to form said terpolymer and without the formation of substantial amounts of particulates or phase separation occurring.
公开/授权文献
- US5456821A Catalytic conversion with improved catalyst 公开/授权日:1995-10-10
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