发明授权
- 专利标题: Production of dichlorobenzene with high para to ortho ratios
- 专利标题(中): 生产具有高对比率的二氯苯
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申请号: US467332申请日: 1990-01-19
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公开(公告)号: US5001290A公开(公告)日: 1991-03-19
- 发明人: Melville Hillman , James D. Browning
- 申请人: Melville Hillman , James D. Browning
- 申请人地址: OH Columbus
- 专利权人: Battelle Memorial Institute
- 当前专利权人: Battelle Memorial Institute
- 当前专利权人地址: OH Columbus
- 主分类号: B01J8/02
- IPC分类号: B01J8/02 ; B01J27/128 ; C07C17/12
摘要:
A method for producing p-dichlorobenzene using a reactor containing a catalyst/reagent to convert chlorobenzene (or benzene) to p-dichlorobenzene, the reactor having an inlet and an outlet for introducing reactants and removing product; introducing a pulse of gaseous chlorobenzene (or benzene) into the reactor and reacting the chlorobenzene with the catalyst/reagent whereby p-dichlorobenzene is formed; introducing a pulse of inert gas into the reactor; introducing a pulse of gaseous chlorine into the reactor and reacting the chlorine with the catalyst/reagent; introducing a pulse of inert gas into the reactor; repeating the pulsing steps in a sequential manner, whereby mixing of the vaporized benzene or chlorobenzene, and the chlorine gas is prevented; and continuously removing product containing p-dichlorobenzene from the outlet of the reactor.
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