发明授权
US5003089A Preparation of cyclic 6-membered to 8-membered vinylene-1,2-dioxy
compounds
失效
环状6元至8元亚乙烯基-1,2-二氧化合物的制备
- 专利标题: Preparation of cyclic 6-membered to 8-membered vinylene-1,2-dioxy compounds
- 专利标题(中): 环状6元至8元亚乙烯基-1,2-二氧化合物的制备
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申请号: US379412申请日: 1989-07-13
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公开(公告)号: US5003089A公开(公告)日: 1991-03-26
- 发明人: Franz Merger , Juergen Frank , Wolfgang Hoelderich , Toni Dockner , Manfred Sauerwald
- 申请人: Franz Merger , Juergen Frank , Wolfgang Hoelderich , Toni Dockner , Manfred Sauerwald
- 申请人地址: DEX Ludwigshafen
- 专利权人: Basf Aktiengesellschaft
- 当前专利权人: Basf Aktiengesellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX3826303 19880803
- 主分类号: B01J29/04
- IPC分类号: B01J29/04 ; C07B61/00 ; C07C43/13 ; C07C47/198 ; C07D319/06 ; C07D319/08 ; C07D319/12 ; C07D321/08 ; C07D321/10 ; C07D321/12 ; C07D335/02 ; C07D495/10 ; C07D521/00
摘要:
Cyclic 6-membered to 8-membered 1,2-vinylenedioxy compounds of the general formula I ##STR1## where A is ##STR2## R.sup.1 to R.sup.7 independently of one another are each hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.2 -C.sub.16 -alkoxyalkyl, C.sub.2 -C.sub.8 -alkenyl, C.sub.2 -C.sub.8 -alkynyl, C.sub.5 -C.sub.8 -cycloalkyl, aryl, C.sub.7 -C.sub.10 -alkylphenyl, C.sub.7 -C.sub.10 -phenalkyl, C.sub.8 -C.sub.10 -phenalkenyl or a heterocyclic structure, or R.sup.2 and R.sup.3, R.sup.2 and R.sup.4, R.sup.3 and R.sup.4, R.sup.2 and R.sup.6, R.sup.3 and R.sup.6, R.sup.4 and R.sup.5 or R.sup.6 and R.sup.7 together form a cycloaliphatic or heterocyclic ring, and R.sup.1 to R.sup.7 may furthermore carry substituents which are inert under the reaction conditions, and n is 0 or 1, are prepared by a process in which a cyclic 2-oxymethyl-1,3-dioxa compound or one of its derivatives of the general formula II ##STR3## where R.sup.1 to R.sup.7, A and n have the abovementioned meanings, and R.sup.8 is hydrogen or C.sub.1 -C.sub.12 -alkyl, is converted in the presence of an acidic catalyst at from 150.degree. to 450.degree. C. and under from 0.001 to 50 bar, some of the compounds obtained being novel.