发明授权
- 专利标题: Conversion of 1,3-dioxanes to 4-oxaaldehydes
- 专利标题(中): 1,3-二恶烷转化为4-氧杂醛
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申请号: US385925申请日: 1989-07-27
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公开(公告)号: US5012005A公开(公告)日: 1991-04-30
- 发明人: Wolfgang Hoelderich , Franz Merger
- 申请人: Wolfgang Hoelderich , Franz Merger
- 专利权人: Wolfgang Hoelderich,Franz Merger
- 当前专利权人: Wolfgang Hoelderich,Franz Merger
- 优先权: DEX3715755 19870512
- 主分类号: C07C45/60
- IPC分类号: C07C45/60 ; C07C47/198 ; C07C47/277 ; C07D335/02
摘要:
4-oxaaldehydes of the formula ##STR1## are prepared by catalytic isomerization of 1,3-dioxanes by a process in which a 1,3-dioxane of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.4 and R.sup.5 are identical or different and are each hydrogen, a straight-chain or branched alkyl, alkenyl or alkynyl radical of not more than 18 carbon atoms, a cycloalkyl or cycloalkenyl radical of 5 to 8 carbon atoms, an aryl, alkylaryl, aralkyl, aralkenyl or alkenylaryl radical of 5 to 16 carbon atoms or a heterocyclic radical and furthermore R.sup.1 and R.sup.2 and/or R.sup.4 and R.sup.5 together with the carbon atoms to which they are bonded may form a cycloalkane, a cycloalkene or a heterocyclic structure, and the stated radicals may furthermore carry substituents which are inert under the reaction conditions, and R.sup.3 is hydrogen or straight-chain or branched alkyl, is isomerized using a metal oxide catalyst, which has been treated with an acid, and/or a silica phase having a zeolite structure.
公开/授权文献
- US4402848A Bar of soap 公开/授权日:1983-09-06