发明授权
- 专利标题: Continuous production of acrylonitrile filaments and fibers from spinning material of low residual solvent content
- 专利标题(中): 由纺丝材料连续生产丙烯腈长丝和纤维,残留溶剂含量低
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申请号: US409550申请日: 1989-09-19
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公开(公告)号: US5013502A公开(公告)日: 1991-05-07
- 发明人: Ulrich Reinehr , Rolf-Burkhard Hirsch , Hermann Josef Jungverdorben , Joachim Dross
- 申请人: Ulrich Reinehr , Rolf-Burkhard Hirsch , Hermann Josef Jungverdorben , Joachim Dross
- 申请人地址: DEX Leverkusen
- 专利权人: Bayer Aktiengesellschaft
- 当前专利权人: Bayer Aktiengesellschaft
- 当前专利权人地址: DEX Leverkusen
- 优先权: DEX3832870 19880928
- 主分类号: D01D5/04
- IPC分类号: D01D5/04 ; D01F6/18 ; D01F6/38 ; D01F11/06 ; D02G1/16 ; D02J1/22
摘要:
A process for the production of crimped filaments and fibers of acrylonitrile polymers of copolymers containing at least 40% by weight acrylonitrile units, by dry spinning from highly polar solvents, where the filaments are brought to extremely low solvent contents in the actual spinning tube by a minimum of superheated steam prepared in the absence of water at very high spinning tube temperatures and spinning gas temperatures, but are cooled to low filament temperatures in the spinning tube by application of water or aqueous finishes in a quantity equivalent to more than 10% by weight moisture. In this way, spun PAN filaments of good natural color are safely obtained, in which there is no washing stage and no drying stage. Acrylic fibers and filaments combining a vacuolestable structure with a very high degree of whiteness and gloss are thus obtained with densities of at least 1.180 g/cm.sup.3, giving shrinkage-free to high-shrinkage fibers, depending on the aftertreatment applied.
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