发明授权
- 专利标题: Wholly aromatic polyester film
- 专利标题(中): 纯粹的芳香聚酯薄膜
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申请号: US365729申请日: 1989-06-14
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公开(公告)号: US5053481A公开(公告)日: 1991-10-01
- 发明人: Toshinori Ishii , Masanori Sato
- 申请人: Toshinori Ishii , Masanori Sato
- 申请人地址: JPX Kurashiki
- 专利权人: Kuraray Co., Ltd.
- 当前专利权人: Kuraray Co., Ltd.
- 当前专利权人地址: JPX Kurashiki
- 优先权: JPX63-150437 19880617
- 主分类号: B29C55/12
- IPC分类号: B29C55/12 ; B29K67/00 ; B29L7/00 ; C08G63/06 ; C08G63/682 ; C08J5/18
摘要:
A wholly aromatic polyester film, (A) which is made of a wholly aromatic polyester consisting essentially of the following recurring units I and II ##STR1## wherein the aromatic ring may be optionally substituted with at least one substituent selected from the group consisting of an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, a halogen atom and a phenyl group, said wholly aromatic polyetser comprising 10 to 90 mol % of the recurring unit I and 90 to 10 mol % of the recurring unti II, being capable of forming an optically anisotropic melt phase, and having a melt strength at a temperature 20.degree. C. higher than its transition temperature to liquid crystal of at least 2.0 g/mm.sup.2 ; (B) said film having an oxygen permeability of not more than 1.0 cc. 20 .mu./m.sup.2. day. atm at a temperature 20.degree. C. and a relative humidity 65%; and (C) said film having thermal shrinkages both in the machine direction and in a direction perpendicular thereto of not more than 1% at a temperature 250.degree. C. Said wholly aromatic polyester film can be produced by melt-extruding a wholly aromatic polyester to form into a film under conditions that a shear rate applied to the wholly aromatic polyester in a molten state at the exit of the molding die is not less than 500 sec.sup.-1.
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