发明授权
- 专利标题: Procedure for gas-phase polymerication of ethylene allowing the fabrication of linear polyethylene with a narrow molecular-weight distribution
- 专利标题(中): 用于具有窄分子量分布的线性聚乙烯的制备的乙烯的气相聚合方法
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申请号: US447670申请日: 1989-12-08
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公开(公告)号: US5055535A公开(公告)日: 1991-10-08
- 发明人: Roger Spitz , Claude Brun , Jean-Francois Joly
- 申请人: Roger Spitz , Claude Brun , Jean-Francois Joly
- 申请人地址: FRX Pateaux
- 专利权人: Atochem
- 当前专利权人: Atochem
- 当前专利权人地址: FRX Pateaux
- 优先权: FRX8816470 19881214
- 主分类号: C08F2/34
- IPC分类号: C08F2/34 ; C08F4/00 ; C08F4/60 ; C08F4/609 ; C08F4/649 ; C08F10/00
摘要:
A process for the manufacture of a linear polyethylene with narrow molecular-weight distribution comprising polymerizing ethylene alone or a mixture of ethylene and an alpha-olefin in which ethylene represents at least about 70% by weight of the total monomers involved, in a gas-phase polymerization medium in the presence of a catalytic component containing at least one transition metal, magnesium, and a halogen, a co-catalyst comprising an alkylaluminum compound, and a monoether, the monoether having the general formula R'OR", wherein R' and R" are the same or different and each is a C.sub.1 to C.sub.8 linear or branched hydrocarbon radical or being a cyclic monoether with the oxygen forming a ring having 4 to 12 carbon atoms.
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