发明授权
- 专利标题: Process for preparation of polyphenylene-sulfide resins in the absence of specific polymerization assistants
- 专利标题(中): 在特定聚合助剂不足情况下制备聚苯乙烯树脂的方法
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申请号: US423565申请日: 1989-10-16
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公开(公告)号: US5071949A公开(公告)日: 1991-12-10
- 发明人: Yoshiaki Nakamura , Kazuyoshi Nagaki , Yuichiro Shiro , Kazuhiro Kawamata
- 申请人: Yoshiaki Nakamura , Kazuyoshi Nagaki , Yuichiro Shiro , Kazuhiro Kawamata
- 申请人地址: JPX Tokyo
- 专利权人: Tohpren Co., Ltd.
- 当前专利权人: Tohpren Co., Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX61-074183 19860402
- 主分类号: C08G75/02
- IPC分类号: C08G75/02 ; C08G75/06
摘要:
Disclosed is a process for the preparation of polyphenylene-sulfide resins, wherein an aromatic polyhalide compound is reacted with an alkali metal sulfide, or hydrogen sulfide and an alkali metal base, or an alkali metal hydrosulfide and an alkali metal base in the presence of an amide polar solvent. A polyphenylene-sulfide resin having a cyclic oligomer content lower than 1.5% by weight, as determined according to the methylene chloride extraction method, is obtained by (a) carrying out the reaction in the absence a polymerization assistant, (b) using the amide polar solvent in an amount not larger than 400 g per mole of the aromatic polyhalide compound, and (c) subjecting the polymerization liquid obtained by the reaction to hot solid-liquid separation at a temperature at least 50.degree. C. but lower than the boiling point of the solvent used, and washing the separated solid with the solvent used for the reaction, which is heated at a temperature at least 50.degree. C. but lower than the boiling point of the solvent.
公开/授权文献
- US5663681A Apparatus and method for stabilizing an amplifier 公开/授权日:1997-09-02
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