发明授权
- 专利标题: Process and catalyst composition for producing olefin polymers
- 专利标题(中): 用于生产烯烃聚合物的方法和催化剂组合物
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申请号: US331221申请日: 1989-03-31
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公开(公告)号: US5075396A公开(公告)日: 1991-12-24
- 发明人: Norio Kashiwa , Akinori Toyota , Mamoru Kioka
- 申请人: Norio Kashiwa , Akinori Toyota , Mamoru Kioka
- 申请人地址: JPX Tokyo
- 专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX57-225999 19821224
- 主分类号: C08F4/00
- IPC分类号: C08F4/00 ; C08F4/46 ; C08F4/60 ; C08F4/64 ; C08F4/658 ; C08F10/00
摘要:
A process for producing a polymer or copolymer of an olefin which comprises polymerizing or copolymerizing at least one olefin with or without a diolefin in the presence of a catalyst composed of (A) a magnesium-containing solid titanium catalyst component containing magnesium, titanium, a halogen and an electron donor as essential ingredients and (B) an organoaluminum compound catalyst component; characterized in that(1) said catalyst further comprises (C) an organic silicon compound catalyst component having an Si--O--C or Si--N--C bond, and(2) said electron donor in the catalyst component (A) is a cyclic mono- or poly-ester such as diethyl furane-3,4-dicarboxylate, di-n-butyl 3,4-dihydro-2H-pyrane-5,6-dicarboxylate, di-isobutyl pyrrole-2,3-dicarboxylic, di-n-butyl thiophene-2,3-dicarboxylate, n-octyl pyrrolidine-2,3-dicarboxylate, and so on.
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