发明授权
US5116923A Hydrophobically associating polymers containing dimethyl acrylamide
functionality
失效
疏水缔合含二甲基丙烯酰胺官能团的聚合物
- 专利标题: Hydrophobically associating polymers containing dimethyl acrylamide functionality
- 专利标题(中): 疏水缔合含二甲基丙烯酰胺官能团的聚合物
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申请号: US545011申请日: 1990-06-28
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公开(公告)号: US5116923A公开(公告)日: 1992-05-26
- 发明人: Jan Bock , Paul L. Valint
- 申请人: Jan Bock , Paul L. Valint
- 申请人地址: NJ Florham Park
- 专利权人: Exxon Research and Engineering Company
- 当前专利权人: Exxon Research and Engineering Company
- 当前专利权人地址: NJ Florham Park
- 主分类号: C08F220/56
- IPC分类号: C08F220/56
摘要:
This invention describes novel hydrophobically associating ter or tetra polymers which can contain sulfonate functionality which are useful as aqueous fluid rheology or flow modifiers. These high molecular weight water soluble polymers contain both water soluble and water insoluble monomers. The water soluble monomers are N, N dimethylacrylamide acrylamide (DMA) and optionally a salt of an ethylenically unsaturated sulfonic acid (s) or N-vinylpyrrolidinone or a metal acrylate and the water insoluble monomer is a higher alkyl acrylamide (R). The process for their preparation relies on solubilizing the water insoluble monomer into an aqueous micellar solution containing one or more surfactants and the water soluble monomers. The surfactants are specifically selected to enable homogeneous dispersion of the hydrophobic monomer(s) in the presence of anionic sulfonate containing monomers. Redox or free radical initiators are used to copolymerize both the water soluble and water insoluble monomers, forming terpolymers of dimethylacrylamide, alkylacrylamides and acrylamide, and optionally an anionic sulfonate or carboxylate monomer. Aqueous solutions of these hydrophobically associating polymers exhibit enhanced viscosification, reduced salt sensitivity and other desirable rheological properties found useful in a variety of applications.
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