Provided is a method and circuit for measuring on a real-time basis trace constituents in vehicle engine exhaust. The control circuit operates to maintain a small, constant concentration of a selected electrolyte constituent reactive with the exhaust constituent sought to be measured. The amount of current necessary to regenerate and maintain the concentration of the selected electrolyte constituent is continuously measured to generate a real-time electrical signal proportional to the mass flow of the exhaust constituent entering the electrochemical cell.