发明授权
- 专利标题: Catalyst for olefinic hydrocarbon polymerization and process for producing olefinic hydrocarbon polymer
- 专利标题(中): 烯烃聚合催化剂和生产烯烃聚合物的方法
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申请号: US675823申请日: 1991-03-27
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公开(公告)号: US5122493A公开(公告)日: 1992-06-16
- 发明人: Hayato Saba , Keisaku Yamamoto , Akio Imai , Kiyoyuki Sugimori , Kizuku Wakatsuki
- 申请人: Hayato Saba , Keisaku Yamamoto , Akio Imai , Kiyoyuki Sugimori , Kizuku Wakatsuki
- 申请人地址: JPX Osaka
- 专利权人: Sumitomo Chemical Co., Ltd.
- 当前专利权人: Sumitomo Chemical Co., Ltd.
- 当前专利权人地址: JPX Osaka
- 优先权: JPX2-084526 19900329; JPX3-7627 19910125
- 主分类号: C08F4/60
- IPC分类号: C08F4/60 ; C08F4/68 ; C08F10/00
摘要:
An inert hydrocarbon solvent-soluble catalyst for polymerization of olefinic hydrocarbons and a process for producing an olefinic polymer using the same are disclosed, the catalyst being composed of (A) a reaction product obtained by reacting (a) at least one vanadium compound represented by formula:VO(OR).sub.m X.sub.3-mwherein R represents a hydrocarbon group; X represents a halogen atom; and m represents a real number of from 0 to 3, and (b) a dihydroxy hydrocarbon compound constituted of a straight chain hydrocarbon skeleton containing from 2 to 12 carbon atoms and having a hydroxyl group at each of both terminals thereof and at least one hydrocarbon branch bonded to said hydrocarbon skeleton in an inert hydrocarbon solvent at an (a) to (b) molar ratio of from 1:0.5 to 1:1.4 and (B) at least one organoaluminum compound represented by formula:R'.sub.n AlX'.sub.3-nwherein R' represents a hydrocarbon group X' represents a halogen atom; and n represents a real number more than 0 and less than 3. Olefinic hydrocarbon polymers having narrow distributions of molecular weight and composition can be produced with high efficiency and high polymerization activity without being accompanied by obstruction or contamination of equipment due to precipitation of a catalyst.
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