发明授权
US5126447A Process for preparation of .beta.-lactam derivative from an alkenyl
substituted .beta.-lactam derivative using a ruthenium or rhenium
catalyst and a periodic acid
失效
使用钌或铑催化剂和周期酸从碱性取代(BETA)-LACTAM衍生物衍生得到的(BETA)-LACTAM衍生物的方法
- 专利标题: Process for preparation of .beta.-lactam derivative from an alkenyl substituted .beta.-lactam derivative using a ruthenium or rhenium catalyst and a periodic acid
- 专利标题(中): 使用钌或铑催化剂和周期酸从碱性取代(BETA)-LACTAM衍生物衍生得到的(BETA)-LACTAM衍生物的方法
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申请号: US662605申请日: 1991-03-01
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公开(公告)号: US5126447A公开(公告)日: 1992-06-30
- 发明人: Sigeru Torii , Hideo Tanaka , Masatoshi Taniguchi , Michio Sasaoka , Takashi Shiroi , Ryo Kikuchi , Yutaka Kameyama
- 申请人: Sigeru Torii , Hideo Tanaka , Masatoshi Taniguchi , Michio Sasaoka , Takashi Shiroi , Ryo Kikuchi , Yutaka Kameyama
- 申请人地址: JPX Osaka
- 专利权人: Otsuka Kagaku Kabushiki Kaisha
- 当前专利权人: Otsuka Kagaku Kabushiki Kaisha
- 当前专利权人地址: JPX Osaka
- 优先权: JPX2-52445 19900302
- 主分类号: B01J23/36
- IPC分类号: B01J23/36 ; B01J23/46 ; C01B11/22 ; C07B61/00 ; C07D205/085 ; C07D205/095 ; C07D403/04 ; C07D405/14 ; C07F7/18
摘要:
A process for preparing a .beta.-lactam derivative of formula (2) and/or the corresponding enol tautomer, which includes oxidizing an alkenyl-substituted .beta.-lactam derivative of formula (1) in the presence of a ruthenium catalyst or a rhenium catalyst using a periodic acid: ##STR1## wherein R.sup.1 is a hydrogen atom, a C.sub.1-4 alkyl group or a C.sub.1-4 haloalkyl group, R.sup.2 is a hydrogen atom, a C.sub.1-4 alkyl group or a phenyl group which may have a substituent, A is a group selected from ##STR2## wherein R.sup.3 is an amino group or a protected amino group, and R.sup.4 -R.sup.8 are as defined in the application.
公开/授权文献
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