发明授权
- 专利标题: Olefin polymerization catalyst component
- 专利标题(中): 烯烃聚合催化剂组分
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申请号: US635632申请日: 1991-01-07
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公开(公告)号: US5130283A公开(公告)日: 1992-07-14
- 发明人: Masahide Murata , Hiroyuki Furuhashi , Akira Nakano , Teruo Yashiro , Seizaburo Kanazawa , Masafumi Imai
- 申请人: Masahide Murata , Hiroyuki Furuhashi , Akira Nakano , Teruo Yashiro , Seizaburo Kanazawa , Masafumi Imai
- 申请人地址: JPX Tokyo
- 专利权人: Tonen Corporation
- 当前专利权人: Tonen Corporation
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX1-121416 19890517
- 主分类号: C08F4/60
- IPC分类号: C08F4/60 ; C08F4/654 ; C08F4/658 ; C08F10/00
摘要:
According to the present invention, there is provided a catalyst component of metal oxide support type which has a high catalytic activity, that is, a little catalyst residue in a polymer, as well as improved catalytic grain strength sufficient for practical use and which hardly deteriorates even after storage for a long time. The catalyst component is obtained by contacting(a) a metal oxide with(b) a dihydrocarbyl magnesium, then contacting the resulting composition with(c) a compound represented by the general formula X.sup.1 .sub.n M(OR.sup.1).sub.m-n wherein X.sup.1 is a hydrogen atom, halogen atom or a hydrocarbon group of 1 to 20 carbon atoms, M is a boron, carbon, aluminum, silicon or phosphorus atom, R.sup.1 is a hydrocarbon group of 1 to 20 carbon atoms, m is the atomic valence of M and m>n.gtoreq.0, and(d) a titanium alkoxide represented by the general formula Ti(OR.sup.2).sub.4 wherein R.sup.2 is a hydrocarbon group of 1 to 12 carbon atoms, and then contacting the resulting solid with (e) an olefin in the presence of (f) an organoaluminum compound, then with (g) a halogen-containing alcohol and further with (h) an electron donating compound and (i) a titanium compound.
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