发明授权
- 专利标题: Preparation of oxidation-stable and low-temperature-stable base oils and middle distillates
- 专利标题(中): 氧化稳定和低温稳定的基础油和中间馏分的制备
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申请号: US654883申请日: 1991-02-01
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公开(公告)号: US5143595A公开(公告)日: 1992-09-01
- 发明人: Juergen Thomas , Roland Spahl , Thomas Anstock , Ansgar Eisenbeis , Wolfgang Schmid
- 申请人: Juergen Thomas , Roland Spahl , Thomas Anstock , Ansgar Eisenbeis , Wolfgang Schmid
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX4003175 19900203
- 主分类号: B01J27/18
- IPC分类号: B01J27/18 ; B01J29/04 ; C10G45/12 ; C10G65/12 ; C10M101/02 ; C10N20/00 ; C10N20/02 ; C10N30/02 ; C10N30/08 ; C10N30/10 ; C10N40/25
摘要:
A process for the preparation of a base oil and middle distillate which is stable to oxidation and low temperature from a mineral oil fraction having a boiling range above 350.degree. C., by, in a first step, converting the mineral oil fraction on a hydrocracking catalyst under hydrocracking conditions to an extent of from 20 to 80% by weight into fractions which boil below 360.degree. C., separating the reactor effluent, if necessary, into liquid and gas phases in a high-pressure separator, treating the entire reactor effluent or only the liquid phase, directly or after removal of the fractions boiling below 360.degree. C. by distillation, in a second step with hydrogen at from 200.degree. to 450.degree. C. and at from 20 to 150 bar in the presence of a catalyst which contains a crystalline pentasil-type borosilicate zeolite, alumina and/or amorphous alumosilicate as the carrier material and one or more metals from Group VIb and/or Group VIII of the Periodic Table and phosphorus, and, after distillation of the hydrogenation product, obtaining a middle distillate in the boiling range from 180.degree. to 360.degree. C. having a pour point of below -30.degree. C. and an oxidation-stable residue having a boiling point >360.degree. C., a viscosity index of from 110 to 135 and a pour point of below -12.degree. C.
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