发明授权
US5147954A 4-(N-benzyl-N-methylamino)pyridine acid salts and use in preparation of
polymer-supported catalysts
失效
4-(N-苄基-N-甲基氨基)吡啶酸盐,并用于制备聚合物负载的催化剂
- 专利标题: 4-(N-benzyl-N-methylamino)pyridine acid salts and use in preparation of polymer-supported catalysts
- 专利标题(中): 4-(N-苄基-N-甲基氨基)吡啶酸盐,并用于制备聚合物负载的催化剂
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申请号: US609393申请日: 1990-11-05
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公开(公告)号: US5147954A公开(公告)日: 1992-09-15
- 发明人: Donald W. McQuigg , Edward E. Sowers , Gerald L. Goe , Eric F. V. Scriven , James G. Keay
- 申请人: Donald W. McQuigg , Edward E. Sowers , Gerald L. Goe , Eric F. V. Scriven , James G. Keay
- 申请人地址: IN Indianapolis
- 专利权人: Reilly Industries Inc.
- 当前专利权人: Reilly Industries Inc.
- 当前专利权人地址: IN Indianapolis
- 主分类号: C07D213/74
- IPC分类号: C07D213/74 ; C08F12/26
摘要:
A cross-linked polymer-supported 4-(N-benzyl-N-methylamino) pyridine material and process for its preparation in high yield and having effective physical and catalytic properties. The polymer-supported catalyst is characterized by the suspension copolymerization of an organic phase containing the corresponding vinyl-substituted pyridine monomer, a styrene monomer, and a suitable cross-linking agent and free radical-generating catalyst in the presence of an aqueous phase containing a cellulose ether derivative as the stabilizing agent. A purified acid salt of the vinyl-substituted pyridine monomer useful in polymerizations and stable for storage as either a solid or an aqueous solution.
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