This invention relates to divinyl ether siloxanes having the formula ##STR1## wherein Y is alkylene or phenylene optionally substituted with fluorine,R is alkylene or alkylene phenylene,R.sub.1 and R.sub.2 are lower alkyl,A is --CH.sub.2 -- or ##STR2## Z is C.sub.2 and C.sub.3 alkylene, B is halo or lower alkyl,m has a value of from 1 to 10,n has a value of from 1 to 20,r has a value of from 0 to 20,t has a value of from 1 to 100 andv has a value of from 0 to 4.The invention also relates to the process of preparing the present divinyl ether siloxanes and to their use as coating materials.