发明授权
US5162517A Process for the preparation of epimer-free sugar alcohols from the group consisting of xylitol, sorbitol (D-glucitol), 4-O-.beta.-D-galactopyranosyl-D-glucitol and 4-O-.alpha.-D-glucopyranosyl-D-sorbitol 失效
由XYLITOL,SORBITOL(D-GLUCITOL),4-O-(BETA)-D-葡萄糖醛酸-D-GLUCITOL和4-O-(ALPHA)-D-葡萄糖苷组合的组中制备无无糖酒精的方法, 葡萄糖醛酸-D-SORBITOL

  • 专利标题: Process for the preparation of epimer-free sugar alcohols from the group consisting of xylitol, sorbitol (D-glucitol), 4-O-.beta.-D-galactopyranosyl-D-glucitol and 4-O-.alpha.-D-glucopyranosyl-D-sorbitol
  • 专利标题(中): 由XYLITOL,SORBITOL(D-GLUCITOL),4-O-(BETA)-D-葡萄糖醛酸-D-GLUCITOL和4-O-(ALPHA)-D-葡萄糖苷组合的组中制备无无糖酒精的方法, 葡萄糖醛酸-D-SORBITOL
  • 申请号: US585747
    申请日: 1990-09-20
  • 公开(公告)号: US5162517A
    公开(公告)日: 1992-11-10
  • 发明人: Gerhard Darsow
  • 申请人: Gerhard Darsow
  • 申请人地址: DEX Leverkusen
  • 专利权人: Bayer Aktiengesellschaft
  • 当前专利权人: Bayer Aktiengesellschaft
  • 当前专利权人地址: DEX Leverkusen
  • 优先权: DEX3934457 19891014; DEX3934458 19891014; DEX3939058 19891125; DEX4000839 19900113
  • 主分类号: C07H15/04
  • IPC分类号: C07H15/04 B01J23/74 C07B61/00 C07C29/132 C07C29/145 C07C31/18 C07C31/26
Process for the preparation of epimer-free sugar alcohols from the group
consisting of xylitol, sorbitol (D-glucitol),
4-O-.beta.-D-galactopyranosyl-D-glucitol and
4-O-.alpha.-D-glucopyranosyl-D-sorbitol
摘要:
The sugar alcohols given in the title can be prepared in epimer-free form from the corresponding sugars by catalytic hydrogenation in aqueous solution using hydrogen, the hydrogenation being carried out continuously at 100-500 bar of H.sub.2 and 60.degree.-125.degree. C. on a fixed bed of carrier-free mouldings composed of pressed powders of the elements of the iron group of the periodic table. The mouldings have a compressive strength of above 50 N and an internal surface of 10-90 m.sup.2 /g.
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