发明授权
US5179051A High density lithium-based ceramics from zeolites 失效
来自沸石的高密度锂基陶瓷

  • 专利标题: High density lithium-based ceramics from zeolites
  • 专利标题(中): 来自沸石的高密度锂基陶瓷
  • 申请号: US808399
    申请日: 1991-12-16
  • 公开(公告)号: US5179051A
    公开(公告)日: 1993-01-12
  • 发明人: Robert L. BedardEdith M. Flanigen
  • 申请人: Robert L. BedardEdith M. Flanigen
  • 申请人地址: IL Des Plaines
  • 专利权人: UOP
  • 当前专利权人: UOP
  • 当前专利权人地址: IL Des Plaines
  • 主分类号: C04B35/19
  • IPC分类号: C04B35/19
High density lithium-based ceramics from zeolites
摘要:
This invention relates to a process for preparing a lithium containing ceramic article. The process provides a ceramic article that is substantially crack free and has as its principal crystalline phase a beta-eucryptite phase, a beta-spodumene phase, or a mixture thereof. The process comprises calcining a powder of a lithium-exchanged zeolite up to its collapse temperature for a time sufficient to collapse the zeolite framework and provide an amorphous powder. The amorphous powder is now formed into a shaped article and sintered at a temperature of about 700.degree. to about 1150.degree. C. for a time of about 1 to about 12 hours. The zeolites which can be used are those having a SiO.sub.2 Al.sub.2 O.sub.3 ratio of about 2 to about 8.5 and include zeolite B, zeolite ZK-19, zeolite W, phillipsite, hormotome, gismondine and mixtures thereof and have a sodium content less than about 1 weight percent. It is preferred that the lithium-exchanged zeolite have an average particle size of less than about 10 microns.
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