发明授权
- 专利标题: Process for preparing unsaturated dicarboxylic acid diesters
- 专利标题(中): 制备不饱和二羧酸的工艺
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申请号: US696053申请日: 1991-05-06
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公开(公告)号: US5189198A公开(公告)日: 1993-02-23
- 发明人: Takashi Kumazawa , Tetsuo Ishibashi , Mitsugu Kanzawa
- 申请人: Takashi Kumazawa , Tetsuo Ishibashi , Mitsugu Kanzawa
- 申请人地址: JPX Tokyo
- 专利权人: Idemitsu Petrochemical Co., Ltd.
- 当前专利权人: Idemitsu Petrochemical Co., Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX2-125568 19900517; JPX2-181648 19900711; JPX2-270373 19901011; JPX2-272401 19901012; JPX3-036566 19910207
- 主分类号: C07C67/38
- IPC分类号: C07C67/38
摘要:
A process for efficiently preparing an unsaturated dicarboxylic acid diester, which comprises reacting a conjugated diene, carbon monoxide, an alcohol and oxygen in the presence of a catalyst comprising (a) a platinum metal, a salt thereof or a complex compound of a platinum metal, (b) at least one metal salt selected from the group consisting of a copper salt, an iron salt and a manganese salt and (C) at least one compound selected from the group consisting of (1) an alkali metal compound or an alkaline earth metal compound, (2) a rare earth metal compound, (3) a metal compound of the groups IIIA, IVA, IVB, VA, VB or VIA, and (4) a metal carbonyl complex. The unsaturated dicarboxylic acid diester is useful as an intermediate material in industrial chemical processes and can be efficiently prepared without the use of a dehydrating agent.