发明授权
- 专利标题: Process for the manufacture of 1-bromoalkyl hydrocarbyl carbonates
- 专利标题(中): 制备1-溴烷基烃基碳酸酯的方法
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申请号: US794842申请日: 1991-11-21
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公开(公告)号: US5202454A公开(公告)日: 1993-04-13
- 发明人: Gary Wooden , Gerard Sennyey , Jean-Pierre Senet
- 申请人: Gary Wooden , Gerard Sennyey , Jean-Pierre Senet
- 申请人地址: FRX Paris
- 专利权人: Societe Nationale des Poudres et Explosifs
- 当前专利权人: Societe Nationale des Poudres et Explosifs
- 当前专利权人地址: FRX Paris
- 优先权: FRX8610185 19860711
- 主分类号: C07C68/06
- IPC分类号: C07C68/06
摘要:
The invention relates to a new process for the preparation of 1-bromoalkyl hydrocarbyl carbonates.The carbonates according to the invention are prepared by reacting an alpha-chlorinated carbonate of formula ##STR1## with an anhydrous brominated compound of formula ZBr in which Z represents hydrogen, the group (CH.sub.3).sub.3 -Si-, the group ##STR2## or bromine if R.sub.2 is other than an aromatic radical, in the presence of a catalyst chosen from the group consisting of heteroaromatic amines, quaternary ammonium or phosphonium halides, hexasubstituted guanidinium halides, alkaline earth metal halides or alkali metal halides in combination with a complexing agent for their cation.The carbonates according to the invention find their preferential applications as blocking agents for some antibiotics or as agents for the synthesis of phosphorus-containing carbonates which can be used as insecticides.