发明授权
- 专利标题: Noble metal on rare earth modified silica alumina as hydrocarbon conversion catalyst
- 专利标题(中): 贵金属稀土改性二氧化硅作为烃转化催化剂
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申请号: US842863申请日: 1992-02-27
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公开(公告)号: US5208200A公开(公告)日: 1993-05-04
- 发明人: Stuart L. Soled , Gary B. McVicker , William E. Gates
- 申请人: Stuart L. Soled , Gary B. McVicker , William E. Gates
- 申请人地址: NJ Florham Park
- 专利权人: Exxon Research and Engineering Co.
- 当前专利权人: Exxon Research and Engineering Co.
- 当前专利权人地址: NJ Florham Park
- 主分类号: B01J21/12
- IPC分类号: B01J21/12 ; B01J23/63 ; B01J37/02 ; C07C5/27
摘要:
Rare earth oxides, such as Nd.sub.2 O.sub.3 disperse onto the surface of SiO.sub.2 /Al.sub.2 O.sub.3 and act as weakly basic titrants. This lowers the acidity of SiO.sub.2 /Al.sub.2 O.sub.3 to close to that of chlorided alumina, as shown by model compound reaction tests. This support also disperses a noble metal such as Pt much better than undoped SiO.sub.2 /Al.sub.2 O.sub.3 and similar to chlorided alumina. Platinum on the rare earth modified silica alumina can function as a hydrocarbon conversion catalyst in reactions where Pt/chlorided Al.sub.2 O.sub.3 is used, such as in reforming, and isomerization, especially wax isomerization.
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