发明授权
US5212127A Process for reactivating a deactivated dehydrocyclodimerization catalyst
失效
重新激活失活的脱氢环化二聚催化剂的方法
- 专利标题: Process for reactivating a deactivated dehydrocyclodimerization catalyst
- 专利标题(中): 重新激活失活的脱氢环化二聚催化剂的方法
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申请号: US790315申请日: 1991-11-08
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公开(公告)号: US5212127A公开(公告)日: 1993-05-18
- 发明人: Joseph A. Kocal , Christopher D. Gosling , Paul J. Kuchar , Tamotsu Imai
- 申请人: Joseph A. Kocal , Christopher D. Gosling , Paul J. Kuchar , Tamotsu Imai
- 申请人地址: IL Des Plaines
- 专利权人: UOP
- 当前专利权人: UOP
- 当前专利权人地址: IL Des Plaines
- 主分类号: B01J29/90
- IPC分类号: B01J29/90 ; B01J38/66 ; C07C2/76
摘要:
This invention relates to a process for reactivating a dehydrocyclodimerization catalyst. Dehydrocyclodimerization catalysts which contain an aluminum phosphate binder can be deactivated when they are exposed to hydrogen at temperatures above 500.degree. C. The instant process restores substantially all of the catalyst's lost activity. The process involves treating the catalyst with an aqueous solution of a weakly acidic ammonium salt or a dilute acid solution at a temperature of about 50.degree. to about 100.degree. C. for a time of about 1 to about 48 hours. An ammonium nitrate solution is preferred. Next the catalyst is calcined at a temperature of about 500.degree. to about 700.degree. C. for a time of about 1 to about 15 hours to provide a reactivated catalyst. The catalyst can be reactivated several times using this process.
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