发明授权
- 专利标题: Process for producing ethylene polymers
- 专利标题(中): 生产乙烯聚合物的方法
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申请号: US827012申请日: 1992-01-28
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公开(公告)号: US5214114A公开(公告)日: 1993-05-25
- 发明人: Tadashi Takahashi , Junji Mayumi , Yoichi Maeda
- 申请人: Tadashi Takahashi , Junji Mayumi , Yoichi Maeda
- 申请人地址: JPX Tokyo
- 专利权人: Mitsubishi Petrochemical Company Limited
- 当前专利权人: Mitsubishi Petrochemical Company Limited
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX3-8393 19910128
- 主分类号: C08F4/658
- IPC分类号: C08F4/658 ; C08F2/06 ; C08F4/60 ; C08F10/00 ; C08F10/02 ; C12N5/06 ; C12N5/10
摘要:
A process for preparing an ethylene polymer which comprises polymerization of ethylene or ethylene and an .alpha.-olefin having 3 to 10 carbon atoms over a catalyst comprising the following components (A) and (B): (A) which is a solid component for a Ziegler catalyst obtained by bringing (2) into contact with (1) and bringing the contact product into contact with (3) and (4) wherein (1) is a solid catalyst component comprising (i)-(iii) where (i): MgX.sub.2, (ii): titanium tetraalkoxide and/or a polytitanate ester, (iii): a polymeric silicon compound, having a formula of ##STR1## R.sup.1 being a hydrocarbyl group, (2) is a halogenated Si compound; (3) is a halohydrocarbon; (4) is an organo-Al compound; and (B) is an organo-Al compound.An ethylene polymer having a moderately broad molecular weight distribution can be prepared in a high activity by use of the catalyst. The ethylene polymer is suited for the production of fibers or tapes.