发明授权
US5235105A Process for the production of pure 3,3',4,4'-tetraamino-biphenyl
失效
制备3,3',4,4'-四氨基苯乙烯的方法
- 专利标题: Process for the production of pure 3,3',4,4'-tetraamino-biphenyl
- 专利标题(中): 制备3,3',4,4'-四氨基苯乙烯的方法
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申请号: US910653申请日: 1992-07-08
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公开(公告)号: US5235105A公开(公告)日: 1993-08-10
- 发明人: Edgar Vorwerk
- 申请人: Edgar Vorwerk
- 申请人地址: DEX Frankfurt am Main
- 专利权人: Hoechst Aktiengesellschaft
- 当前专利权人: Hoechst Aktiengesellschaft
- 当前专利权人地址: DEX Frankfurt am Main
- 优先权: DEX4123033 19910712
- 主分类号: B01J27/122
- IPC分类号: B01J27/122 ; C07B61/00 ; C07C209/10 ; C07C209/84 ; C07C211/50
摘要:
The present invention relates to a process for the preparation of pure 3,3',4,4'-tetraaminobiphenyl in high yield by ammonolysis of 3,3,-dichlorobenzidine in the presence of copper powder and CuCl. After the crude product has been washed with ammonia water and water, the 3,3',4,4'-tetraaminobiphenyl, thus pretreated, is crystallized in water in the presence of 0 to 5% by weight of activated carbon and of about 1 to 2% by weight of a water-soluble reducing agent at temperatures of about 100.degree. to about 140.degree. C., under a protective gas atmosphere (redissolution). The water-soluble reducing agent is an alkali metal dithionite or alkali metal sulfite. The protective gas used can be nitrogen. The water used in the recrystallization (redissolution water) can be reused in whole or in part in the recrystallization.