发明授权
US5240894A Method for making and using a supported metallocene catalyst system
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制备和使用负载型金属茂催化剂体系的方法
- 专利标题: Method for making and using a supported metallocene catalyst system
- 专利标题(中): 制备和使用负载型金属茂催化剂体系的方法
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申请号: US885170申请日: 1992-05-18
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公开(公告)号: US5240894A公开(公告)日: 1993-08-31
- 发明人: Terry J. Burkhardt , Masahide Murata , William B. Brandley
- 申请人: Terry J. Burkhardt , Masahide Murata , William B. Brandley
- 申请人地址: NJ Linden
- 专利权人: Exxon Chemical Patents Inc.
- 当前专利权人: Exxon Chemical Patents Inc.
- 当前专利权人地址: NJ Linden
- 主分类号: C08F4/658
- IPC分类号: C08F4/658 ; C08F4/02 ; C08F4/60 ; C08F4/619 ; C08F4/6192 ; C08F4/659 ; C08F4/6592 ; C08F10/00 ; C08F110/02 ; C08F110/06 ; C08F210/16
摘要:
The invention relates to a novel process for producing a supported metallocene catalyst system useful for the polymerization and/or copolymerization of olefins, alpha-olefins, and/or diolefins which results in a catalyst product which during polymerization, produces minimal to no reactor fouling and polymer of controlled morphology. The invention is particularly useful for but not limited to polymerizing propylene or copolymerizing propylene with olefins having two or more carbon atoms. The novel support technique described herein results in a catalyst which will obtain polymer product having controlled, uniform particle size, narrow molecular weight distribution, high bulk density and depending upon the metallocene employed and monomers polymerized, stereoregularity.
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