发明授权
- 专利标题: Composition for photo imaging
- 专利标题(中): 摄影成像的组成
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申请号: US918304申请日: 1992-07-21
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公开(公告)号: US5264325A公开(公告)日: 1993-11-23
- 发明人: Robert D. Allen , Richard A. Day , Donald H. Glatzel , William D. Hinsberg , John R. Mertz , David J. Russell , Gregory M. Wallraff
- 申请人: Robert D. Allen , Richard A. Day , Donald H. Glatzel , William D. Hinsberg , John R. Mertz , David J. Russell , Gregory M. Wallraff
- 申请人地址: NY Armonk
- 专利权人: International Business Machines Corporation
- 当前专利权人: International Business Machines Corporation
- 当前专利权人地址: NY Armonk
- 主分类号: G03F7/038
- IPC分类号: G03F7/038 ; G03F7/20 ; H05K3/00 ; H05K3/28 ; D04H1/08
摘要:
An improved photoimagable cationically polymerizable epoxy based coating material is provided, that is suitable for use on a variety of substrates. The material includes an epoxy resin system consisting essentially of between about 10% and about 80% by weight of a polyol resin which preferably is a condensation product of epichlorohydrin and bisphenol A having a molecular weight of between about 40,000 and 130,000; and between about 35% and 72% by weight of an epoxidized glycidyl ether of a brominated bisphenol A having a softening point of between about 60.degree. C. and about 110.degree. C. and a molecular weight of between about 600 and 2,500. A third resin, either an epoxy cresol novolak or a polyepoxy resin, is also added to the resin system. To this resin system is added about 0.1 to about 15 parts by weight per 100 parts of resin of a cationic photoinitiator capable of initiating polymerization of said epoxidized resin system upon exposure to actinic radiation; the system being further characterized by having an absorbance of light in the 330 to 700 nm region of less than 0.1 for a 2.0 mil thick film. Optionally a photosensitizer such as perylene and its derivatives or anthracene and its derivatives may be added.