发明授权
- 专利标题: Method for the preparation of a stabilized catalyst for the polymerization of olefins
- 专利标题(中): 烯烃聚合稳定催化剂的制备方法
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申请号: US43626申请日: 1993-04-07
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公开(公告)号: US5296430A公开(公告)日: 1994-03-22
- 发明人: Hideo Funabashi , Yoichi Matsuo , Shigeo Iwasaki
- 申请人: Hideo Funabashi , Yoichi Matsuo , Shigeo Iwasaki
- 申请人地址: JPX Tokyo
- 专利权人: Idemitsu Petrochemical Company, Ltd.
- 当前专利权人: Idemitsu Petrochemical Company, Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX1-242030 19890920
- 主分类号: C08F4/651
- IPC分类号: C08F4/651 ; C08F10/00
摘要:
A so-called Ziegler catalyst composed of a titanium halide-containing solid ingredient and an organoaluminum compound for the polymerization of olefins can be imparted with greatly improved storage stability by first subjecting the catalytic composition to a pre polymerization treatment and then to a contacting treatment with carbon dioxide and/or carbon monoxide. The catalytic activity is almost unchanged even after storage of the stabilized catalyst for 90 days or longer in nitrogen gas. The stabilized catalyst can also be used advantageously in a continuous-process polymerization of propylene by continuously introducing the monomer carrying the catalyst owing to absence of blocking of the pipe line with the polymer formed in-line.
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