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US5298594A Preparation of nylon 6 with alkali metal hypophosphite catalyst and organic phosphite catalyst 失效
用碱金属次磷酸盐催化剂和有机亚磷酸盐催化剂制备尼龙6

Preparation of nylon 6 with alkali metal hypophosphite catalyst and
organic phosphite catalyst
摘要:
A method for the polymerization of Nylon 6 from caprolactam and water using a catalyst composition comprising a primary catalyst, which can be an alkali metal hypophosphite or an alkali-earth metal hypophosphite, and an organic phosphite as cocatalyst. The catalyst composition used in this invention is most useful when used in conjunction with the reactive extrusion technology which requires a very fast polymerization rate to take full advantage of this evolving technology.
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