发明授权
US5300586A Hydroxyl functional derivatives of epoxidized diene block copolymers and
process for making them (II)
失效
环氧二烯嵌段共聚物的羟基官能衍生物及其制备方法(II)
- 专利标题: Hydroxyl functional derivatives of epoxidized diene block copolymers and process for making them (II)
- 专利标题(中): 环氧二烯嵌段共聚物的羟基官能衍生物及其制备方法(II)
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申请号: US863648申请日: 1992-04-03
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公开(公告)号: US5300586A公开(公告)日: 1994-04-05
- 发明人: Robert C. Bening , James R. Erickson , David J. St. Clair , Carma J. Gibler , Joe J. Flores
- 申请人: Robert C. Bening , James R. Erickson , David J. St. Clair , Carma J. Gibler , Joe J. Flores
- 申请人地址: TX Houston
- 专利权人: Shell Oil Company
- 当前专利权人: Shell Oil Company
- 当前专利权人地址: TX Houston
- 主分类号: C08C19/40
- IPC分类号: C08C19/40 ; C08F8/00 ; C08G18/62 ; C09D175/04
摘要:
A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.
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