发明授权
- 专利标题: Process for the preparation of d,1-menthol
- 专利标题(中): 制备d,1-薄荷醇的方法
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申请号: US28850申请日: 1993-03-10
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公开(公告)号: US5300706A公开(公告)日: 1994-04-05
- 发明人: Otto Immel , Gerhard Darsow , Hans-Josef Buysch
- 申请人: Otto Immel , Gerhard Darsow , Hans-Josef Buysch
- 申请人地址: DEX Leverkusen
- 专利权人: Bayer Aktiengesellschaft
- 当前专利权人: Bayer Aktiengesellschaft
- 当前专利权人地址: DEX Leverkusen
- 优先权: DEX4208443 19920317
- 主分类号: B01J23/656
- IPC分类号: B01J23/656 ; B01J27/055 ; C07B61/00 ; C07C29/20 ; C07C35/12 ; C07C29/00 ; C07C29/17
摘要:
A process for the preparation of d,l-menthol by catalytic hydrogenation of aromatic or partly hydrogenated cyclic compounds which have the carbon skeleton of menthol having at least one double bond and are substituted by oxygen in the 3-position relative to the methyl group, with simultaneous rearrangement of optically active or inactive stereoisomers of menthol at elevated temperature and under pressure is described. The hydrogenation, which is to be carried out continuously, is carried out on a fixed bed catalyst which comprises, as active constituents, palladium, ruthenium or rhodium or a mixture of these elements, and comprises alkali metal hydroxides and/or alkali metal sulphates as promoters; the support for this catalyst is doped with a rare earth metal and manganese.
公开/授权文献
- US6107574A Sealing article 公开/授权日:2000-08-22
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