发明授权
US5345008A Decomposition of organic hydroperoxides with nitrated porphyrin complexes
失效
有机氢过氧化物与硝化卟啉配合物的分解
- 专利标题： Decomposition of organic hydroperoxides with nitrated porphyrin complexes
- 专利标题（中）： 有机氢过氧化物与硝化卟啉配合物的分解
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申请号： US73840申请日： 1993-06-09
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公开(公告)号： US5345008A公开(公告)日： 1994-09-06
- 发明人: James E. Lyons , Paul E. Ellis, Jr.
- 申请人： James E. Lyons , Paul E. Ellis, Jr.
- 申请人地址： PA Philadelphia
- 专利权人： Sun Company, Inc. (R&M)
- 当前专利权人： Sun Company, Inc. (R&M)
- 当前专利权人地址： PA Philadelphia
- 主分类号： B01J31/22
- IPC分类号： B01J31/22 ; C07B61/00 ; C07C27/00 ; C07C29/132 ; C07C29/50 ; C07C31/12 ; C07C37/08 ; C07C45/53 ; C07C29/48 ; C07C31/00 ; C07C33/00
摘要：
Hydroperoxides are decomposed by contact with metalloporphyrin coordination complex catalysts in which hydrogen in the porphyrin molecule has been substituted with at least one nitro group and may be further substituted with other electron-withdrawing elements or groups, for example, halogen or halocarbons, or with hydrocarbon groups. Preferred catalysts are iron tetranitro-.beta.-octaethylporphyrins and iron tetrakispentafluorophenyl-.beta.-nitroporphyrins.
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