发明授权
- 专利标题: Process for the preparation of 1,3-propanediol by the hydrogenation of hydroxypropionaldehyde
- 专利标题(中): 通过羟基丙醛氢化制备1,3-丙二醇的方法
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申请号: US948718申请日: 1992-09-24
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公开(公告)号: US5364984A公开(公告)日: 1994-11-15
- 发明人: Dietrich Arntz , Thomas Haas , Adolf Schafer-Sindlinger
- 申请人: Dietrich Arntz , Thomas Haas , Adolf Schafer-Sindlinger
- 申请人地址: DEX Frankfurt
- 专利权人: Degussa Aktiengesellschaft
- 当前专利权人: Degussa Aktiengesellschaft
- 当前专利权人地址: DEX Frankfurt
- 优先权: DEX4132663 19911001
- 主分类号: B01J23/42
- IPC分类号: B01J23/42 ; C07B61/00 ; C07C29/141 ; C07C31/20
摘要:
Disclosed is a process for the preparation of 1,3-propanediol by the hydrogenation of hydroxypropionaldehyde (HPA) in aqueous solution on a formed carrier catalyst in a solid bed, the concentration of HPA in the solution being from 5 to 100% by weight and hydrogenation being carried out at temperatures of from 30.degree. to 180.degree. C. and hydrogen pressures of from 5 to 300 bar and at a pH of from 2.5 to 6.5. The carrier catalyst is formed principally of titanium oxide on which platinum is applied in a finely divided form in a quantity of from 0.1 to 5.0% by weight, based on the carrier.
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