发明授权
US5364984A Process for the preparation of 1,3-propanediol by the hydrogenation of hydroxypropionaldehyde 失效
通过羟基丙醛氢化制备1,3-丙二醇的方法

Process for the preparation of 1,3-propanediol by the hydrogenation of
hydroxypropionaldehyde
摘要:
Disclosed is a process for the preparation of 1,3-propanediol by the hydrogenation of hydroxypropionaldehyde (HPA) in aqueous solution on a formed carrier catalyst in a solid bed, the concentration of HPA in the solution being from 5 to 100% by weight and hydrogenation being carried out at temperatures of from 30.degree. to 180.degree. C. and hydrogen pressures of from 5 to 300 bar and at a pH of from 2.5 to 6.5. The carrier catalyst is formed principally of titanium oxide on which platinum is applied in a finely divided form in a quantity of from 0.1 to 5.0% by weight, based on the carrier.
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