发明授权
- 专利标题: Process for the production of cyclohexanedimethanol
- 专利标题(中): 环己烷二甲醇生产方法
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申请号: US174321申请日: 1993-12-30
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公开(公告)号: US5387752A公开(公告)日: 1995-02-07
- 发明人: John Scarlett , Michael A. Wood , Colin Rathmell
- 申请人: John Scarlett , Michael A. Wood , Colin Rathmell
- 申请人地址: TN Kingsport
- 专利权人: Eastman Chemical Company
- 当前专利权人: Eastman Chemical Company
- 当前专利权人地址: TN Kingsport
- 优先权: GBX9324783 19931202
- 主分类号: B01J23/86
- IPC分类号: B01J23/86 ; C07B61/00 ; C07C29/136 ; C07C29/149 ; C07C31/27
摘要:
A process is described for the production of cyclohexanedimethanol by hydrogenation of a dialkyl cyclohexanedicarboxylate which comprises:(a) providing a hydrogenation zone containing a charge of a granular heterogeneous ester hydrogenation catalyst;(b) forming a vaporous feed stream of a hydrogen-containing gas,and a hydrogenatable material comprising a dialkyl cyclohexanedicarboxylate at a feed temperature which is in the range of from about 150.degree. C. to about 350.degree. C. and which is above the dew point of the feed stream and at a feed pressure in the range of from about 150 psia (about 10.34 bar) to about 2000 psia (about 137.90 bar), said vaporous feed stream having a known hydrogen-containing gas:dialkyl cyclohexanedicarboxylate ratio;(c) supplying the vaporous feed stream to the hydrogenation zone;(d) maintaining hydrogenation conditions in the hydrogenation zone which are effective to maintain the reaction mixture in contact with the hydrogenation catalyst above its dew point;(e) passing the vaporous feed stream through the hydrogenation zone; and(f) recovering from the hydrogenation zone a product stream containing cyclohexanedimethanol.In this process it is preferred to use dimethyl 1,4-cyclohexanedicarboxylate to produce 1,4-cyclohexanedimethanol.
公开/授权文献
- US5913319A Hair binder 公开/授权日:1999-06-22
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